Preheat the oven to 400°F, 200°C or gas mark 6. Season both sides of the pork chops with salt, garlic powder, and paprika.
In a pan over medium high heat the olive oil. Add the pork chops and sear each side cooking for 2-3 minutes per side. Place in the oven and cook for another 7-10 minutes or until the internal temperature reaches 145°F or 63°C.
While the pork chops are cooking in a mixing bowl combine the balsamic vinegar, brown sugar, honey, mustard see, oregano, and red chili flakes. Whisk to combine. In a small bowl mix the cornstarch with 1 tablespoon of water to make a slurry.
Add the balsamic mixture to a pan and heat until it starts to boil. Quickly stir in the cornstarch mixture and keep stirring until it has thickened. Remove from heat and set aside.
Once the pork chops are done add them to the pan with the glaze and spoon the glaze over the pork chops to coat evenly.